Triphenylphosphite as a good reagent for the diasteroselective synthesis of phosphonate esters

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Multi-component Process for the Synthesis of Some Phosphonate Derivatives using Water as a Green Solvent

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Synthesis of Pyrrole Phosphonate Esters: Emphasis on Pyrrole NH Acids and Dialkylacetylenic Esters Substitution

Reaction of dialkyl acetylenedicarboxylates 1a-c andpyrrole derivatives 2a-e in the presence of triphenylphosphite (TPP) was investigated and the effect of the pyrrole substitution was established. Diastereoselectivity is observed with pyrroles, 2a,b, yieldingphosphonate ester derivatives 3a-f and 4,and their relative configuration is determined by 1H/13C and 31</...

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synthesis of pyrrole phosphonate esters: emphasis on pyrrole nh acids and dialkylacetylenic esters substitution

reaction of dialkyl acetylenedicarboxylates 1a-c andpyrrole derivatives 2a-e in the presence of triphenylphosphite (tpp) was investigated and the effect of the pyrrole substitution was established. diastereoselectivity is observed with pyrroles, 2a,b, yieldingphosphonate ester derivatives 3a-f and 4,and their relative configuration is determined by 1h/13c and 31p nmr and confirmed by single x-r...

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ژورنال

عنوان ژورنال: Arkivoc

سال: 2006

ISSN: 1551-7012

DOI: 10.3998/ark.5550190.0007.c17